Prep Beef: Pat beef dry. Toss slices with 2 tbsp cornstarch until lightly coated.
Mix Sauce: Whisk soy sauce, brown sugar, water, garlic, ginger, rice vinegar, sesame oil, red pepper flakes, and 1 tsp cornstarch until smooth.
Cook Veg: Heat 1 tbsp oil in a large skillet on medium-high. Sauté broccoli and bell pepper with a pinch of salt 3–4 minutes until crisp-tender. Transfer out.
Sear Beef: Add remaining 1 tbsp oil. Sear beef in a single layer 1–2 minutes per side until browned (work in batches if needed). Add green onion whites.
Sauce + Combine: Pour in sauce, simmer 30–60 seconds to thicken and glaze. Return veggies, toss to coat.
Build Bowls: Divide rice among 4 meal prep containers. Top with Mongolian beef and veggies. Garnish with green onion greens and sesame seeds.